Grade 10

Grade 10Carbon and its compounds


Important organic reactions (combustion, addition, substitution, polymerization)


Combustion, addition, substitution, polymerization

Organic reactions involve compounds containing carbon. Understanding these reactions is important in chemistry, as they form the basis of many processes in our daily lives. Here we examine the four major types of organic reactions: combustion, addition, substitution, and polymerization. Each of these plays an important role in both industrial applications and biological systems.

Combustion

Combustion is a type of chemical reaction in which a substance combines with oxygen to produce heat and usually light. This process is essential for providing energy and is commonly seen in the burning of fuels such as wood, coal, and gasoline.

Combustion may be classified into two types:

  • Complete combustion: Occurs when a hydrocarbon reacts with enough oxygen, forming carbon dioxide and water. For example, the combustion of methane is represented as:
  •  CH 4 + 2O 2 → CO 2 + 2H 2 O
  • Incomplete combustion: This occurs when the supply of oxygen is limited, producing carbon monoxide or carbon (soot) along with water. Incomplete combustion of methane can be expressed as:
  •  2CH 4 + 3O 2 → 2CO + 4H 2 O

    In real life, combustion is clearly visible in car engines, heating systems, and even in the metabolic processes of living organisms.

    Oxygen

Addition reaction

Addition reactions are common with unsaturated hydrocarbons such as alkenes and alkynes. These molecules have double or triple bonds, which can open to add new atoms.

The addition reaction can be represented as:

 Unsaturated compound + New Atom(s) → Saturated compound

Consider the reaction of ethane (C 2 H 4 ) with hydrogen (H 2 ) to form ethane (C 2 H 6 ):

 C 2 H 4 + H 2 → C 2 H 6

These reactions are used in many industries, for example, the production of margarine by hydrogenation of vegetable oils.

C 2 H 4 , H2 C 2 H 6

Addition reactions are important in the production of polymers, which we will study in depth in the polymerization section.

Substitution reaction

In substitution reactions, an atom or group of atoms in a molecule is replaced by another atom or group. This type of reaction often occurs in saturated hydrocarbons or aromatic compounds.

The simplest representation of a substitution reaction is as follows:

 RH + X → RX + H

Where R is an alkyl group and X is a substituent.

An everyday example of this is the chlorination of methane:

 CH 4 + Cl 2 → CH 3 Cl + HCl

Substitution reactions are important in organic synthesis, allowing chemists to incorporate different functional groups into organic molecules.

CH 4 , CL 2 CH 3 Cl , HCl

The use of catalysts or light in such reactions can increase the rate of the substitution process.

Polymerization

Polymerization involves the formation of larger molecules called polymers from smaller units called monomers. This process is fundamental in the manufacture of many synthetic materials such as plastics, fibers and rubber.

Polymerization reactions can be classified into addition polymerization and condensation polymerization:

  • Addition polymerization: Monomers add to each other without loss of any molecule. A typical example of this is the polymerization of ethene to form polyethylene:
  •  nC 2 H 4 → [-CH 2 -CH 2 -] n
  • Condensation polymerization: monomers join together with the elimination of small molecules such as water or methanol. An example of this is the formation of nylon from hexamethylenediamine and adipic acid:
  •  nHOOC-(CH 2 ) 4 -COOH + nH 2 N-(CH 2 ) 6 -NH 2 → [-OC-(CH 2 ) 4 -CO-NH-(CH 2 ) 6 -NH-] n + 2nH 2 O

Polymerization supports a wide range of applications, from everyday materials like plastic bags and bottles to advanced biomedical devices.

N C 2 H 4 [-CH 2 -CH 2 -] n polyethylene

With polymerization, the versatility and broadness of the materials that can be synthesized meet a wide variety of needs, from practical uses in construction to complex applications in electronics.

Conclusion

The four types of organic reactions: combustion, addition, substitution, and polymerization, are fundamental to the study and application of chemistry. Each reaction type makes important contributions to both everyday life and industrial processes. Understanding these reactions helps explain how various materials are developed and used in the world around us.


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