Grade 10 → Acids, Bases and Salts ↓
Properties and Definitions of Acids and Bases (Arrhenius, Bronsted-Lowry, Lewis)
Understanding acids and bases is fundamental in chemistry. Acids and bases have unique properties that make them important in a variety of chemical reactions and applications. In this comprehensive guide, we will explore the three major theories that define acids and bases: Arrhenius, Bronsted-Lowry, and Lewis.
Arrhenius theory
In 1887, Svante Arrhenius proposed one of the first modern definitions of acids and bases. According to
Arrhenius, an acid is a substance that increases the concentration of hydrogen ions, H +
,
in an aqueous solution, while a base increases the concentration of hydroxide ions, OH -
.
Properties of Arrhenius acid
- They taste sour. For example, lemons contain citric acid.
- They turn blue litmus paper red.
- They react with metals such as zinc to produce hydrogen gas.
- They increase the concentration of
H +
ions in water.
Properties of Arrhenius bases
- They taste bitter and are slippery, like soap.
- They turn red litmus paper blue.
- They increase the concentration of
OH -
ions in water.
Example
HCl (aq) → H + (aq) + Cl - (aq) NaOH (aq) → Na + (aq) + OH - (aq)
Bronsted–Lowry theory
Johannes Bronsted and Thomas Lowry independently proposed a more general theory in 1923. In the Bronsted-Lowry theory, an acid is a proton donor, and a base is a proton acceptor. This theory expands on Arrhenius by including reactions outside of aqueous solution.
Acid-base reaction examples
NH 3 + H 2 O ⇌ NH 4 + + OH -
In this reaction, water acts as a Bronsted-Lowry acid by donating a proton to ammonia
(NH 3
), forming an ammonium ion (NH 4 +
) and a hydroxide ion
(OH -
).
Visual representation
Lewis theory
Gilbert N. Lewis proposed an even more comprehensive theory in 1923. According to Lewis, acids are electron pair acceptors, while bases are electron pair donors. This definition incorporates all the previous definitions and emphasizes the transfer of electron pairs.
Example of a Lewis acid-base reaction
BF 3 + NH 3 → F 3 B←NH 3
In this reaction, boron trifluoride (BF 3
) acts as a Lewis acid by accepting an electron
pair from ammonia (NH 3
), a Lewis base, forming a coordinate covalent bond.
Visual representation
Comparison of theories
Each principle of acids and bases enhances our understanding of chemical reactions:
- The Arrhenius theory is limited to aqueous solutions and involves basic neutralization reactions.
- The Brønsted–Lowry theory covers a broad range of acidity and basicity by defining acids and bases via proton transfer.
- Lewis theory covers all acids and bases because it considers the transfer of electron pairs, thus explaining many other reactions, including those that do not occur in aqueous solution.
Here is a summary table that shows the various definitions and their examples:
written | Acid | Base | Example response |
---|---|---|---|
Arrhenius | generates H + | produces OH- | HCl + NaOH → NaCl + H 2 O |
Bronsted-Lowry | Proton donor | Proton acceptor | NH 3 + H 2 O ⇌ NH 4 + + OH - |
Lewis | electron pair acceptor | electron pair donor | BF 3 + NH 3 → F 3 B←NH 3 |
Applications of acids and bases
Acids and bases play important roles in a variety of industrial, biological and environmental processes:
- In industrial applications, sulfuric acid (
H 2 SO 4
is used in the manufacture of fertilizers and chemicals. - In biological systems, hydrochloric acid (
HCl
) in the stomach aids digestion. - In environmental science, understanding acid rain caused by sulfuric and nitric acids helps solve pollution problems.
Industrial example
2 NH 3 + H 2 SO 4 → (NH 4 ) 2 SO 4
This equation shows the production of ammonium sulfate, a common fertilizer.
Example from everyday life
NaHCO 3 + CH 3 COOH → CO 2 + H 2 O + CH 3 COONa
In this reaction, baking soda reacts with vinegar to produce carbon dioxide gas—a common school experiment to create a volcano with bubbling lava.
Conclusion
Understanding acids and bases through various principles enhances scientific progress and our ability to predict and control various chemical reactions essential to everyday life. From manufacturing to biology and environmental science, the principles of acids and bases are important for many applications in various fields.