Grade 10 → Metals and Nonmetals ↓
Physical and Chemical Properties of Non-Metals
Nonmetals are one of the major groups of elements that exhibit a range of physical and chemical properties that differ from metals. Nonmetals cover a wide range of elements and can be found in a variety of states at room temperature: gases such as oxygen and nitrogen, liquids such as bromine, and solids such as carbon and sulfur. The diversity among nonmetals is considerable, and they play important roles in natural and man-made processes. Below, we discuss the physical and chemical properties of nonmetals in depth, exploring their unique characteristics with examples and visualizations.
Physical properties of nonmetals
Nonmetals have specific physical properties that distinguish them from metals. Let us examine these properties in detail:
Brittleness
Many non-metals are brittle in their solid state, meaning they break easily when subjected to stress. For example, sulfur is a yellow solid that can easily be broken into powder when beaten with a hammer. In contrast, metals are generally malleable and ductile.
Here is a simplified illustration of the breakage of a brittle nonmetal:
Non-shiny (dull)
Unlike metals, non-metals lack a lustrous appearance and are usually dull. This dullness is more pronounced in solid non-metals such as carbon in the form of coal or graphite. The surfaces of these materials do not reflect light like metallic surfaces.
Poor conduction
Nonmetals are generally poor conductors of heat and electricity. This is because they are unable to allow the free movement of electrons. For example, rubber, which is made of non-metallic elements, is widely used as an insulator in electrical applications.
Low density and low melting point
Nonmetals generally have lower densities and melting points than metals. This property is evident in gases such as oxygen and nitrogen, which are essential components of the Earth's atmosphere. However, there are exceptions such as diamond (a form of carbon), which has a very high melting point.
Form and color
Nonmetals show a variety of colors. For example, chlorine is yellow-green, iodine is purple, and sulfur is yellow. The variety in color is attributed to the different molecular structures that nonmetals can form.
Here is a diagram showing the colors of some common nonmetals:
Chemical properties of nonmetals
The chemical properties of nonmetals are as diverse as their physical properties. They can participate in a wide range of chemical reactions, often act as oxidizing agents, form covalent bonds, and exist in various allotropes.
High electronegativities
Electronegativity refers to the ability of an atom to attract electrons in a covalent bond toward itself. Nonmetals usually have higher electronegativities than metals, causing them to gain electrons during chemical reactions. Oxygen and fluorine have the highest electronegativities.
Electronegativity of Fluorine ≈ 4.0
Covalent bond
Nonmetals usually form covalent bonds by sharing electrons with other nonmetals. These bonds are clearly visible in molecules such as water (H2O
) and carbon dioxide (CO2
).
The covalent bond in water can be represented as follows:
Formation of acidic oxides
Nonmetals usually react with oxygen to form acidic oxides. These oxides dissolve in water to form acids. For example, sulfur dioxide (SO2
) reacts with water to form sulfurous acid:
SO2 + H2O → H2SO3
Miscellaneous oxidation states
Nonmetals often exhibit multiple oxidation states, allowing them to form a wide variety of compounds. For example, nitrogen can exist in different oxidation states, forming compounds such as ammonia (NH3
), nitrogen dioxide (NO2
), and nitric acid (HNO3
).
Tendency to gain electrons
During chemical reactions, nonmetals gain electrons, usually reducing their partners while being oxidized themselves. This property makes nonmetals powerful oxidizing agents.
Allotropes
Many non-metals exhibit allotropy, where they exist in different structural forms. A prime example is carbon, whose allotropes include diamond, graphite, and fullerenes, each of which have distinct properties.
A simplified representation of carbon allotropes can be shown as follows:
Conclusion
Nonmetals play important roles in chemistry and our daily lives. Their unique physical and chemical properties enable them to participate in a wide variety of chemical reactions essential to life, industry, and technology. Understanding these properties allows us to effectively use nonmetals in a variety of applications, from building materials to cutting-edge electronics. This comprehensive look at the properties of nonmetals highlights their importance, which is in contrast yet in harmony with the metals in the vast periodic table.