Grade 10 → Matter and its properties ↓
Law of conservation of mass and law of definite proportions
Chemistry is a fascinating subject that explores the properties, structure, and transformation of matter. At its core, chemistry relies on several fundamental laws to understand how substances interact with one another. Two of these important laws are the law of conservation of mass and the law of definite proportions. These principles form the basis of many chemical reactions and theories. This detailed text aims to provide a comprehensive understanding of these laws with practical examples and illustrations.
Law of conservation of mass
The law of conservation of mass states that in a closed system, the mass of the reactants is equal to the mass of the products. This concept was first formulated by Antoine Lavoisier in the late 18th century. It basically means that mass is neither created nor destroyed in a chemical reaction.
Understanding the law
Imagine you have a sealed container. No matter what chemical reactions are going on inside, as long as nothing enters or leaves the container, the total mass remains unchanged. This allows chemists to predict the outcome of reactions in terms of mass. The equation is simple:
Total mass of reactants = Total mass of products
Illustrative examples
Consider the simple reaction of hydrogen gas reacting with oxygen gas to form water:
2H 2 + O 2 → 2H 2 O
Imagine a balance scale, imagine that on the left is hydrogen and oxygen gas, and on the right is the produced water. The scales should remain balanced before and after the reaction, which means that mass is conserved.
The diagram above shows equal mass on both sides of the scale. This shows that no mass is lost or gained during the reaction.
Daily life applications
This principle is observed when baking cakes. Although the ingredients undergo a complex transformation, the total weight of the starting material remains the same as that of the final baked cake, provided there is no volume loss.
Mathematical example
Consider the reaction of zinc with hydrochloric acid to form zinc chloride and hydrogen gas:
Zn + 2HCl → ZnCl 2 + H 2
Suppose that 65 g of zinc reacts with 73 g of hydrochloric acid, forming 136 g of zinc chloride and 2 g of hydrogen gas. To verify this:
Total mass of reactants: 65 g + 73 g = 138 g.
Total mass of products: 136 g + 2 g = 138 g.
This calculation shows that mass is conserved.
Law of definite proportions
The law of definite proportions, also called the law of constant composition, states that a chemical compound will always have the same proportion of elements by mass. This concept is important to understand that a compound is made up of elements in a fixed proportion, regardless of its source or quantity.
Understanding the law
French chemist Joseph Proust proposed this law in 1794. According to Proust, river water is chemically identical to laboratory water, with a mass ratio of hydrogen and oxygen of 1:8.
Water (H 2 O): Ratio of H to O = 2:16 = 1:8 (by mass)
Illustrative examples
Consider sodium chloride (table salt), which is composed of sodium (Na) and chlorine (Cl):
NaCl
The mass ratio of sodium to chlorine in sodium chloride is consistent with:
Na : Cl = 23 : 35.5
Imagining a pie chart, each quarter of the chart could represent a specific mass portion of the compound, emphasizing that sodium and chlorine are constantly present in each portion, maintaining a fixed ratio.
This diagram shows the specific elemental parts within the sodium chloride compound.
Textual examples
Let's consider carbon dioxide (CO2). No matter where you get CO2 from, whether from burning coal or from a fire, the mass ratio of carbon and oxygen in it is equal to 12:32. This consistent ratio validates the law of definite proportions.
Conceptual application
This principle is important in pharmaceuticals, where maintaining consistency in the proportions of active ingredients in a drug is essential to ensure therapeutic effectiveness. In quality control, manufacturers must guarantee to maintain a stable ingredient composition of products such as beverages worldwide.
Interrelationships between laws
The law of conservation of mass and the law of definite proportions are very closely interconnected. Both laws are the basis of modern stoichiometry used in chemical equations and reactions. They give chemists information about the expected mass output and the required input composition for accurate, predictable reactions.
When combined, these rules enable chemists to understand the balance and proportions of elements in new compounds. For example, by knowing the masses of the reactants, scientists can predict the amount of products that will form by applying these two principles together.
Conclusion
The laws of conservation of mass and definite proportions are fundamental principles in chemistry. They help chemists understand the unchanging nature of mass during chemical reactions and the fixed proportions of elements in compounds. By integrating visual and textual examples, these laws become easier to understand, providing a solid foundation for further exploration in chemistry.