Grade 10

Grade 10Metals and Nonmetals


Extraction of metals from ores


Introduction to metallurgy

Metals are elements that are generally hard, lustrous, malleable, ductile and good conductors of heat and electricity. But did you know that most of the metals used in our daily lives are obtained through a complex process called metallurgy? The process of extracting metals from their ores and refining them for use is called metallurgy.

What are ores?

Ores are naturally occurring rocks or minerals from which metals can be extracted economically. Not all rocks contain metals in appreciable quantities. Ores usually contain abundant native metals such as oxides, sulfides, silicates, or native copper. Some typical examples of ores include:

  • Hematite: An important ore of iron.
  • Bauxite: The primary ore of aluminum.
  • Chalcopyrite: A major ore of copper.

Stages of metallurgy

Metallurgy generally involves three major stages:

  1. Concentration of ore (or enrichment of ore): This is the initial stage of metallurgy, where the ore is extracted from the ground and concentrated to increase the percentage of metal present in it. This process may involve crushing the ore and then using various methods such as gravity separation, magnetic separation, froth flotation, etc.
  2. Conversion of concentrated ore to metal: The concentrated ore is then converted into the actual metal which is the main step in the extraction of metals. This can be through roasting, calcination or chemical reduction.
  3. Refining of metal: The raw metal obtained from the above process is impure, and refining is done to remove these impurities and obtain pure metal. Common methods include electrolytic refining, zone refining, and vapor phase refining.

Concentration of ore

Concentration of the ore is a critical step that ensures that the ore is pure and concentrated enough to allow effective extraction of the metal. It involves separating the valuable metal-bearing minerals from the waste or gangue.

Fe 2 O 3 + 3CO → 2Fe + 3CO 2

Methods of concentration

Let us discuss some common methods of concentration:

  • Gravity Separation: This method is applicable when the ore particles are heavier than the matrix or gangue. Ore
  • Flotation: Used for sulfide ores, the ore is mixed with water to form a slurry, and air bubbles are passed through the slurry, causing the desired minerals to float. WaterBubble
  • Magnetic Separation: This method is used when the ore or impurities are magnetic. Magnet

Conversion of concentrated ore into metal

The concentrated ore is subjected to various processes to extract the metal. Let's take a look at some of these methods:

  • Roasting: It is a process in which the ore is heated in the presence of oxygen, which removes moisture and volatile impurities.
    2ZnS + 3O 2 → 2ZnO + 2SO 2
  • Calcination: Done by heating the ore very strongly in the absence or limited supply of air, resulting in the decomposition of the carbonate ore.
    CaCO 3 → CaO + CO 2
  • Reduction: It involves the chemical conversion of metal oxide into metal by a reducing agent such as carbon, hydrogen or other active metals.
    Fe 2 O 3 + 3CO → 2Fe + 3CO 2

Metal refining

Finally, the metal extracted from the ore is refined to obtain high purity metal. The refining process depends on the nature of the metal and its use in society.

Common methods of purification

  • Electrolytic refining: The impure metal is made the anode, and the pure metal is made the cathode. When electric current is passed through the electrolyte, the pure metal is deposited at the cathode.
    Cu 2+ + 2e - → Cu
    AnodeCathode
  • Zone refining: Used to purify metals containing impurities with low melting points; a heater moves along a rod of impure metal, melting it and carrying the impurities with it.
  • Vapour phase refining: A method in which the impure metal is converted into its volatile compound, and then decomposed to obtain the pure metal.
    TiCl 4 + 2Mg → 2MgCl 2 + Ti

Conclusion

The extraction of metals from ores is a fascinating journey of chemistry and engineering that transforms rocks into valuable resources. Understanding the basic processes of metallurgy not only explains how metals are prepared for manufacturing, but also sheds light on important stages of human advancement and technological development throughout history.


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