Grade 10 → Chemical Reactions and Equations ↓
Exothermic and Endothermic Reactions
Chemical reactions are processes where one or more substances change into one or more different substances. They involve the breaking and formation of bonds between atoms. During these reactions, there is often a change in energy as well. This energy change can result in the absorption or emission of energy. In chemistry, these types of reactions are classified as exothermic or endothermic depending on where the energy goes.
Understanding chemical reactions
In any chemical reaction, bonds in the reactants are broken, and new bonds are formed to form products. Breaking bonds requires energy, while forming bonds releases energy. The difference in energy between these two processes results in a change in the overall energy of the reaction.
Exothermic reactions
Exothermic reactions release energy into the surroundings, usually in the form of heat. This happens when the energy needed to break the bonds in the reactants is less than the energy released when new bonds are formed in the products. As a result, the temperature of the surroundings rises.
A classic example of an exothermic reaction is the combustion of methane gas:
CH 4 + 2O 2 → CO 2 + 2H 2 O + energy
In this reaction, methane (CH 4
) burns in the presence of oxygen (O 2
), resulting in the formation of carbon dioxide (CO 2
) and water (H 2 O
) with the release of energy.
Another example of an exothermic reaction is the reaction between hydrochloric acid and sodium hydroxide:
HCl + NaOH → NaCl + H 2 O + energy
Here, hydrochloric acid reacts with sodium hydroxide to form sodium chloride and water, releasing energy.
Visual example of an exothermic reaction
The diagram above shows an exothermic reaction. Note that the energy level of the products is lower than that of the reactants, indicating the release of energy into the surrounding environment.
Endothermic reactions
Endothermic reactions absorb energy from the surroundings. This happens when more energy is needed to break bonds in the reactants than is released when new bonds are formed in the products. As a result, the temperature of the surroundings decreases.
A well-known example of an endothermic reaction is the thermal decomposition of calcium carbonate:
CaCO 3 + energy → CaO + CO 2
In this reaction, calcium carbonate (CaCO 3
) decomposes to form calcium oxide (CaO
) and carbon dioxide (CO 2
), absorbing energy when heated.
Photosynthesis is another example of an endothermic reaction:
6CO 2 + 6H 2 O + energy → C 6 H 12 O 6 + 6O 2
In this process, plants take in carbon dioxide and water, and produce glucose and oxygen using the sun's energy.
Visual example of an endothermic reaction
The diagram above shows an endothermic reaction. Note that the energy level of the products is higher than that of the reactants, indicating energy absorption from the surroundings.
Comparison of exothermic and endothermic reactions
Criteria | Exothermic reactions | Endothermic reactions |
---|---|---|
Energy transformation | Energy is released. | Energy is absorbed. |
Temperature Change | The surrounding temperature increases. | The surrounding temperature decreases. |
Example | Combustion, neutralization | Photosynthesis, thermal decomposition |
Factors affecting exothermic and endothermic reactions
Several factors affect the energy changes in exothermic and endothermic reactions:
Nature of reactants and products
The type of bonds that are broken and formed plays an important role. Stronger bonds require more energy to break and release more energy when formed. For example, in combustion reactions, the strong carbon-hydrogen bonds in hydrocarbons release a lot of energy when they react with oxygen.
Concentration of reactants
Concentration affects the rate and extent of the reaction. In an exothermic reaction, higher concentrations of reactants usually lead to more energy being released because more molecules are available to react. In endothermic reactions, higher concentrations of reactants can increase the energy absorbed, because more energy is needed to enable the reaction to occur.
Pressure and volume
Changes in pressure and volume can affect reactions, especially those involving gases. Increasing pressure by reducing volume often increases the reaction rate and the energy change in reactions can be altered by affecting the frequency of collisions of molecules.
Temperature
Temperature affects reaction rates and energy changes. In exothermic reactions, increasing the temperature can reduce the amount of net energy released to the surroundings, because some of this energy is used to further increase the temperature. For endothermic reactions, raising the temperature provides the energy needed to break bonds, allowing the reaction to proceed.
Applications and implications
Everyday examples
Exothermic and endothermic reactions are found in everyday life. Heat packs used for warmth involve exothermic reactions, while cooking and baking food, which absorb heat, are examples of endothermic processes.
Industrial applications
In industries, exothermic reactions are used for heating purposes, such as in power plants and manufacturing processes. Endothermic reactions are important in processes such as photosynthesis, which is vital to oxygen production and life on Earth.
Environmental impact
If exothermic reactions are not properly controlled, industrial use can contribute to global warming due to the release of heat and greenhouse gases. Understanding and optimizing these reactions is essential to minimize their environmental impact.