Grade 10 ↓
Chemical bond
Chemical bonding is the process in which atoms or molecules combine to form more complex structures through interactions between electrons. Chemical bonds are important because they hold the building blocks of matter together, contributing to the properties and behavior of substances.
Understanding atoms
An atom consists of a nucleus, which contains protons and neutrons, and electrons that revolve around the nucleus. The number of protons in the nucleus of an atom determines the identity of the element and is known as the atomic number. Electrons orbit the nucleus in different energy levels or shells, and their arrangement is important for bonding.
Electron configuration
Electrons are arranged in shells around the atom's nucleus. The first shell can have up to 2 electrons, the second shell can have up to 8, and so on. The electrons in the outermost shell are called valence electrons, and they are important in chemical bonding.
For example, in a helium atom with 2 electrons: Shell 1: 2 electrons (complete)
In a neon atom with 10 electrons: Shell 1: 2 electrons Shell 2: 8 electrons (complete)
Why do atoms bond together?
Atoms bond to achieve more stable electron configurations. Atoms are generally more stable when their outer electron shells are full, similar to the noble gases that are naturally stable. When atoms react, they lose, gain, or share electrons to fill their outer shells, forming different types of chemical bonds.
Types of chemical bonds
Ionic bond
Ionic bonds form when electrons transfer from one atom to another, forming ions. An ion is an atom that has a net positive or negative charge due to the loss or gain of electrons. This usually occurs between metals and non-metals.
Example of ionic bond:
Sodium (Na) has 1 electron in its outer shell, chlorine (Cl) has 7 electrons. Na (1 valence electron) --> Na⁺ + e⁻ Cl (7 valence electrons) + e⁻ --> Cl⁻ Na⁺ + Cl⁻ --> NaCl
The formation of oppositely charged ions results in an attractive force, forming an ionic bond that holds the ions together in a compound such as sodium chloride (NaCl).
Covalent bonds
Covalent bonds are formed when two atoms share one or more electron pairs. This type of bond usually occurs between non-metal atoms.
Example of covalent bond:
Hydrogen (H) atoms have 1 electron each. By sharing their electrons, they can fill their outer shell, forming covalent bonds: H : H (H₂ single covalent bond)
When the atoms share electrons equally, the bond is a nonpolar covalent bond. If the atoms do not share electrons equally, the bond is called a polar covalent bond.
Metal bonding
Metallic bonds are formed between metal atoms. In this type of bond, electrons are not shared between individual atoms. Instead, electrons move around freely in a 'sea' between the lattice of atoms. This electron mobility is responsible for many of the properties of metals, such as conductivity and malleability.
Examples of bonds in everyday life
Chemical bonds exist everywhere around us. The air we breathe, the food we eat, and the objects we use are all products of atoms bonded in different ways. Understanding how these bonds work enriches our understanding of the physical world.
Common compounds
- Water (H2O): Two hydrogen atoms and one oxygen atom form a covalent bond.
- Carbon dioxide (CO2): One carbon atom forms double covalent bonds with two oxygen atoms.
- Sodium chloride (NaCl): An ionic bond between sodium and chloride ions.
Role of electronegativity in bonding
Electronegativity is a measure of an atom's ability to attract and hold electrons. In general, nonmetals have higher electronegativities than metals. The difference in electronegativities between atoms affects the type of bond that forms:
- If the electronegativities difference is large (usually > 1.7), an ionic bond is likely to form.
- If the difference is small or zero, a covalent bond is formed.
- With a moderate difference (between 0.4 and 1.7), a polar covalent bond is likely, where the electrons are shared unequally.
Example: Na and Cl: high difference, ionic bond. O and H: medium difference, polar covalent bond. F and F: no difference, non-polar covalent bond.
Molecules and compounds
A molecule is a group of two or more atoms held together by covalent bonds. If the atoms are different, the molecule is a compound. Compounds can have completely different properties than the individual elements that make them up.
Example: O₂ - Molecule composed of two oxygen atoms. H₂O - Molecules and compounds composed of hydrogen and oxygen.
Macroscopic properties of substances
The type of chemical bond affects the macroscopic properties of substances:
- Ionic compounds: Usually solid at room temperature, have high melting and boiling points, conduct electricity when melted or dissolved in water.
- Covalent compounds: These may be gases, liquids or solids, have low melting and boiling points, they generally do not conduct electricity.
- Metallic substances: good conductors of electricity and heat, malleable, ductile, lustrous.
Conclusion
Chemical bonding is fundamental to chemistry, enabling the formation of compounds and influencing the properties of substances. Whether through ionic, covalent or metallic bonding, the interactions between atoms create the diverse world of substances seen in nature. Understanding these bonds helps us understand the behavior and transformations of matter.