Grade 10 → Metals and Nonmetals ↓
Reactivity Series of Metals and Displacement Reactions
The study of reactivity series and displacement reactions is an essential part of understanding chemistry, especially when dealing with the behavior of metals. This explanation will highlight the concepts related to these two fundamental topics.
Understanding the reactivity series
The reactivity series is a way of arranging metals (and hydrogen) in order of their reactivity from highest to lowest. This order helps predict the behavior of metals in a reaction. The more reactive the metal, the more vigorous its reactivity will be.
Order of metals in reactivity series
Here is a commonly used reactivity series, listed from most reactive to least reactive:
Potassium (K) > Sodium (Na) > Calcium (Ca) > Magnesium (Mg) > Aluminium (Al) > Zinc (Zn) > Iron (Fe) > Tin (Sn) > Lead (Pb) > (Hydrogen) > Copper (Cu) > Mercury (Hg) > Silver (Ag) > Gold (Au)
Note that hydrogen is included in the series for reference to help predict reactions involving acids.
Examples of reactivity
Reactivity can be observed through various experiments, such as observing bubbles in an acid or how quickly a metal corrodes when exposed to oxygen.
Visual explanation example
In this example, as you move down the list, the reactivity with water decreases.
Factors affecting reactivity
- Atomic structure: Valency and number of losing electrons are important for stability.
- Electron shielding: More electron shells means less friction force between the nucleus and the valence electrons.
- Nuclear force: Metals with lower atomic number have lower nuclear force, which makes them more reactive.
Displacement reactions
Displacement reactions occur when a more reactive metal displaces a less reactive metal from its compound. This is a common chemical reaction seen in metals and tells us about the strength and power of different metals.
General equations and examples:
Metal A + Salt solution (of metal B) → Salt solution (of metal A) + Metal B
If metal A is more reactive than metal B, it will "pull" metal B out of the compound, and take its place.
Textual examples
Zinc + Copper sulphate → Zinc sulphate + Copper
The above equation can be expressed as:
Zn(s) + CuSO 4 (aq) → ZnSO 4 (aq) + Cu(s)
Why do displacement reactions happen?
Displacement occurs due to differences in the reactivity of the metals. If a metal is higher up in the reactivity series, it can displace another metal with lower reactivity. Essentially, the reaction is driven by energy mobility, where the more reactive metal will more easily give up electrons, thus leaving another metal in a position.
Visual example of a displacement reaction
Other examples of displacement reactions
Iron + Copper sulphate → Iron sulphate + Copper
Fe (s) + CuSO 4 (aq) → FeSO 4 (aq) + Cu (s)
- Aluminum and Lead Nitrate:
2Al (s) + 3Pb(NO 3 ) 2 (aq) → 2Al(NO 3 ) 3 (aq) + 3Pb (s)
- Magnesium and Silver Nitrate:
Mg (s) + 2AgNO 3 (aq) → Mg(NO 3 ) 2 (aq) + 2Ag (s)
Applications of reactivity series and displacement reactions
Understanding these reactions has practical applications in real-world scenarios, including:
- Extraction of metals: Metals are often extracted from their ores via displacement reactions.
- Corrosion prevention: Knowledge of the reactivity of metals helps in designing better corrosion resistant materials.
- Electroplating: Electroplating uses displacement reactions to coat one metal with another less reactive metal.
Summary
The study of reactivity series and displacement reactions sheds light on the nature and behaviour of metals. It helps in predicting the outcomes of chemical reactions, thereby enriching our understanding of chemical processes. By analysing these fundamental principles, students can better understand the intricacies of chemistry.