Grade 7 → Chemical bond ↓
Intermolecular forces
Intermolecular forces are forces of attraction or repulsion that act between neighboring particles (atoms, molecules, or ions). They are different from intermolecular forces, which hold atoms together within a molecule or compound. Understanding these forces is important because they determine many physical properties of substances, such as boiling and melting points, solubility, and the state of matter at a given temperature and pressure.
Let's explore the basic types of intermolecular forces: London dispersion forces, dipole-dipole interactions, and hydrogen bonding.
London dispersion force
London dispersion forces are the weakest intermolecular forces. They are caused by temporary fluctuations in electron density that occur in all atoms and molecules. When electrons are asymmetrically distributed, this creates a temporary dipole, which can induce a dipole in a neighboring atom or molecule, resulting in a weak attraction.
These forces are present in all molecules, whether polar or nonpolar. They increase with the size of the electron cloud; larger atoms or molecules with more electrons exhibit stronger London dispersion forces.
Example: Noble gases like helium (He), neon (Ne), argon (Ar).
Visual example:
Dipole–dipole interaction
Dipole-dipole interactions occur between polar molecules; these molecules have permanent dipoles, meaning they have a positive and a negative end. When two polar molecules come close to each other, the positive end of one molecule is attracted to the negative end of the other.
These interactions are stronger than London dispersion forces but weaker than hydrogen bonds. The strength of dipole-dipole interactions depends on the magnitude of the dipoles and the distance between them.
Example: Hydrogen chloride (HCl), where H is slightly positive and Cl is slightly negative.
Visual example:
Hydrogen bonds
A hydrogen bond is a special type of dipole-dipole interaction that occurs when hydrogen is covalently bonded to a highly electronegative atom such as nitrogen (N), oxygen (O), or fluorine (F). The hydrogen atom becomes slightly positive as the electronegative atom pulls electron density away from itself. The slightly positive hydrogen then forms a bond with a lone pair of electrons on the other electronegative atom.
Hydrogen bonds are stronger than both London dispersion forces and dipole-dipole interactions, but they are weaker than covalent or ionic bonds.
The presence of hydrogen bonds explains the unique properties of water, such as its high boiling point and surface tension.
Example: Water (H2O), where H is bonded to O.
Visual example:
Comparison of intermolecular forces
It is necessary to understand the relative strengths of these forces in order to understand how they affect the properties of matter.
- London dispersion force: The weakest type of intermolecular force, present in all molecules.
- Dipole-dipole interactions: Occur between polar molecules, are stronger than London dispersion forces.
- Hydrogen bonds: Formed when hydrogen bonds covalently to N, O, or F, the strongest intermolecular force of the three types described here.
Real-life applications
Intermolecular forces play an important role in everyday life and natural phenomena. For example:
- High boiling point of water: Because of hydrogen bonding, water has a boiling point of 100°C (212°F), which is much higher than other molecules of the same size.
- Surface tension: Water has a higher surface tension than most other liquids because hydrogen bonds form a "film" on the surface.
- Biochemical processes of life: In biological systems, hydrogen bonding is important in maintaining DNA structures and facilitating enzyme functionality.
Factors affecting intermolecular forces
Various factors can affect the strength and effect of intermolecular forces:
- Molecular size: Larger molecules with more electrons usually have stronger London dispersion forces.
- Polarity: More polar molecules will exhibit stronger dipole-dipole interactions.
- Presence of hydrogen bonding: Molecules that can form hydrogen bonds generally have strong intermolecular attractions.
Intermolecular forces are essential for understanding how substances behave in different environments and conditions. Knowledge of these forces can help predict boiling and melting points, solubility, and the general behavior of substances.
Conclusion
In short, intermolecular forces are crucial in determining the physical properties of substances. Although they are weaker than the bonds within molecules, they significantly affect how substances interact with one another. By understanding London dispersion forces, dipole-dipole interactions, and hydrogen bonds, we gain insight into the fascinating behaviors of matter that are essential to both science and the natural world. This fundamental knowledge lays the groundwork for studies in chemistry and beyond.