Grade 8

Grade 8Metals and Nonmetals


Reactivity Series of Metals


The reactivity series of metals is a list of metals arranged in order of decreasing reactivity. The most reactive metal is placed at the top and the least reactive metal at the bottom. Understanding this series helps in explaining and predicting the behaviour of the metal in displacement reactions, its method of extraction and its reactions with water and acids.

Understanding the reactivity series

Reactivity in metals refers to how easily the metal loses its electrons to form positive ions. Metals at the top of the reactivity series, such as potassium (K) and sodium (Na), are highly reactive. They react rapidly with water and oxygen, forming compounds such as KOH (potassium hydroxide) and Na 2 O (sodium oxide).

        K + H2O → KOH + H2
    

This reaction shows that potassium reacts with water to form potassium hydroxide and hydrogen gas.

Order of reactivity

Metals are listed in order from most reactive to least reactive. Here is a simplified list showing the reactivity series:

  • Potassium (K)
  • Sodium (Na)
  • Calcium (Ca)
  • Magnesium (Mg)
  • Aluminum (Al)
  • Zinc (Zn)
  • Iron (Fe)
  • Lead (Pb)
  • Copper (Cu)
  • Silver (Ag)
  • Gold (Au)
  • Platinum (Pt)

In the SVG example, imagine two metal blocks, one representing potassium and the other gold. The potassium block is reacting vigorously with the water, producing bubbles of hydrogen gas, while the gold block is stationary and not reacting with the water.

Potassium Gold

Reactivity and displacement reactions

Displacement reactions occur when a more reactive metal can displace a less reactive metal from its compound. For example, when magnesium is added to a solution of copper sulfate, magnesium will displace copper because magnesium is more reactive:

        Mg + CuSO4MgSO4 + Cu
    

In this reaction magnesium sulphate and copper metal are formed. This type of displacement helps in separating metals during extraction.

Reaction with water

Reactive metals such as sodium and potassium react vigorously with water to form hydrogen gas and metal hydroxides. For the most reactive metals this reaction can be explosive. Here's how sodium reacts with water:

        2Na + 2H 2 O → 2NaOH + H 2
    

Metals lower in the reactivity series, such as iron or copper, do not react with water in the same way.

Reaction with acids

Most metals react with acids to form hydrogen gas and salts. Reactivity depends on the position of the metal in the reactivity series. Here is an example of zinc reacting with hydrochloric acid:

        2HCl + Zn → ZnCl2 + H2
    

Gold and platinum, being at the bottom of the reactivity series, do not react with acids.

Metal removal

The reactivity of a metal determines how it is extracted from its ore. For example, highly reactive metals such as sodium and aluminum are extracted using electrolysis, while less reactive metals such as zinc and iron are extracted by reduction with carbon.

In extraction by electrolysis, metal ions at the electrodes are reduced to form the pure metal. For example, extracting aluminum from aluminum oxide:

        2Al 2 O 3 → 4Al + 3O 2
    

Visualizing the series

Imagine a ladder with metals arranged from the most reactive to the least reactive metal at the top. At the top, you'll find metals that are very reactive and challenging to find as free metals in nature, and at the bottom, you'll find metals like gold, which are often found in their native form.

K Na Ca Mg

This visualization helps illustrate how metals at different reactivity levels might "stand" relative to one another on our reactivity ladder.

Industrial applications

Knowledge of the reactivity series is important in many industrial applications. For example, the galvanization process, where a protective zinc layer is applied to iron or steel to prevent corrosion, involves less reactive iron being displaced by more reactive zinc. Another application is in sacrificial protection, where a more reactive metal such as magnesium is used to protect a less reactive metal such as iron from corrosion.

Chemical vs. physical properties

It is important to distinguish between chemical reactivity and physical properties. For example, the shiny appearance of a metal (a physical property) does not necessarily indicate high reactivity (a chemical property).

Summary

The reactivity series of metals is a valuable tool in chemistry that helps explain a variety of reactions and processes. Knowing the series allows students and scientists to predict the outcomes of reactions, understand extraction methods, and apply this knowledge in practical applications such as the prevention of metal corrosion.


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