Grade 8 → Periodic Table and Chemical Trends ↓
Periodicity and trends in atomic and ionic sizes
In chemistry, understanding how atomic and ionic sizes change across the periodic table is essential to understanding how elements interact in chemical reactions. The periodic table is a powerful tool that reveals trends and patterns among the elements, helping us predict how they will behave.
What are atomic and ionic sizes?
The atomic size of an element refers to the size of the atom, which can be thought of as the distance of the outermost electrons from the nucleus. Alternatively, the ionic size refers to the size of the ion, which is an atom that has lost or gained electrons.
Atom ➝ Na (Sodium) Ion ➝ Na + (Sodium Ion)
Since Na loses electrons to form Na +, the ionic size of Na + is different from the atomic size of Na.
Atomic size in a period
In the periodic table, a row is called a period. The size of the atom decreases as we move from left to right in a period. This trend occurs because protons and electrons get added to atoms as we move from left to right:
Atomic number order ➝ Li, Be, B, C, N, O, F
Visual example: Let's compare the sizes of Li and F atoms.
This happens because the addition of protons increases the positive charge in the nucleus, which pulls the electrons closer to the nucleus, making the atom smaller in size.
Atomic size one group down
In the periodic table, the column is called a group. As you move down a group, the atomic size increases. This increase is due to the addition of new energy levels of electrons:
Vertical order: Li, Na, K, Rb, Cs
Visual example: Compare the size of Li and Cs atoms.
As we move down the group, new electron shells are added, making the atom larger.
Ionic size trends
To understand ionic size it is necessary to examine how the size of an atom changes when it forms an ion. The general rule is:
- When an atom loses electrons to form a cation (positively charged ion), its size decreases.
- When an atom gains an electron and becomes an anion (negatively charged ion), its size increases.
Cation: Na ➝ Na + (small) Anion: Cl ➝ Cl - (large)
Cations
Cations are formed when electrons are removed from an atom. Removing electrons reduces electron-electron repulsion, allowing the remaining electrons to be pulled closer to the nucleus.
Anion
Anions are formed when atoms gain electrons. This gain causes the electron-electron repulsion to increase, which causes the electrons to spread out more, making the ion larger.
Summary of key trends
- Atomic size decreases from left to right in a period.
- The size of the atom increases on going down the group.
- Cations decrease in size when they lose electrons.
- Anions increase in size when they gain electrons.
These trends can help predict the chemical reactivity and properties of elements. By understanding the fluctuations in atomic and ionic size within the periodic table, students can more easily understand why elements behave the way they do in chemical reactions.